Recent Advances in Visible Light Induced Palladium Catalysis
Sarkar, S.; Cheung, K.P.S.; Gevorgyan, V. Angew. Chem., Int. Ed. 2023, 62, e202311972.
Escape from Hydrofunctionalization: Palladium Hydride-Enabled Difunctionalization of Conjugated Dienes and Enynes
Zhang, Z.; Gevorgyan, V. Angew. Chem., Int. Ed. 2023, 62, e202311848.
(Hot Paper)
One-Pot Formal Carboradiofluorination of Alkenes: A Toolkit for Positron Emission Tomography Imaging Probe Development
(Highlighted in Synfacts 2023, 19, 1256)
Merging of Light/Dark Palladium Catalytic Cycles Enables Multicomponent Tandem Alkyl Heck/Tsuji–Trost Homologative Amination Reaction toward Allylic Amines
Kvasovs, N.; Fang, J.; Kliuev, F.; Gevorgyan, V. J. Am. Chem. Soc. 2023, 145, 18497-18505.
(In Top 10 Most Read Articles, Sep 2023)
(Highlighted in Synfacts 2023, 19, 1107)
Enhanced Excited State Hydricity of Pd–H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes
(In Top 20 Most Read Articles, June 2023)
(Highlighted in Synfacts 2023, 19, 0797)
Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis
Iziumchenko, V.; Gevorgyan, V. Synlett 2023, 34, 1289–1308. (Invited Review)
Advances in Selected Heterocyclization Methods
Rivas, M.; Gevorgyan, V. Synlett 2023, 34, 1554–1562. (Invited Account)
Targeting lipid-protein interaction to treat Syk-mediated acute myeloid leukemia
Asymmetric Intermolecular Allylic C–H Amination of Alkenes With Aliphatic Amines
Cheung, K.P.S.; Fang J.; Mukherjee K.; Mihranyan A.; Gevorgyan, V. Science 2022, 378, 1207–1213.
(Highlighted in Synfacts 2023, 19, 0271)
Palladium Hydride-Enabled Hydroalkenylation of Strained Molecules
Zhang, Z.; Gevorgyan, V. J. Am. Chem. Soc. 2022, 144, 20875–20883.
General and selective metal-free radical α-C–H borylation of aliphatic amines
Sarkar, S.; Wagulde, S.; Jia, X.; Gevorgyan, V. Chem 2022, 8, 3096–3108.
Recent advances in visible light-induced C(sp3)–N bond formation
Rivas, M.; Palchykov V.; Jia, X.; Gevorgyan, V. Nat. Rev. Chem. 2022, 6, 544–561.
Accessing Illusive E Isomers of α-Ester Hydrazones via Visible-Light-Induced Pd-Catalyzed Heck-Type Alkylation
Kvasovs, N.; Gevorgyan, V. Org. Lett. 2022, 23, 4176–4181.
Visible-Light-Induced Brønsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones
Zhang, Z.; Kvasovs, N.; Dubrovina, A.; Gevorgyan, V. Angew. Chem., Int. Ed. 2022, 61, e202110924.
(Top Downloaded Article)
Visible Light-Induced Transition Metal Catalysis
Cheung, K.P.S.; Sarkar, S.; Gevorgyan, V. Chem. Rev. 2022, 122, 1543–1625.
Three-Component Visible-Light-Induced Palladium-Catalyzed 1,2-Alkyl Carbamoylation/Cyanation of Alkenes
Jia, X.; Zhang, Z.; Gevorgyan, V. ACS Catal. 2021, 11, 13217–13222.
Visible Light-Induced Pd-Catalyzed Alkyl-Heck Reaction of Oximes
Kvasovs, N.; Iziumchenko, V.; Palchykov, V.; Gevorgyan, V. ACS Catal. 2021, 11, 3749–3754.
Contemporary Methods for Generation of Aryl Radicals
Kvasovs, N.; Gevorgyan, V. Chem. Soc. Rev. 2021, 50, 2244–2259. (Tutorial Review)
C–H Functionalization Reactions Enabled by Hydrogen Atom Transfer to Carbon-Centered Radicals
Sarkar, S.; Cheung, K.P.S.; Gevorgyan, V. Chem. Sci. 2020, 11, 12974–12993. (Perspective)
Co-Catalyzed Transannulation of Pyridotriazoles with Isothiocyanates and Xanthate Esters
Zhang, Z.; Gevorgyan, V. Org. Lett. 2020, 22, 8500–8504.
Denitrogenative Transformations of Pyridotriazoles and Related Compounds: Synthesis of N-Containing Heterocyclic Compounds and Beyond
Yadagiri, D.; Rivas, M.; Gevorgyan, V. J. Org. Chem. 2020, 85, 11030–11046. (Perspective)
Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and Beyond
Cheung, K.P.S.; Kurandina, D.; Yata, T.; Gevorgyan, V. J. Am. Chem. Soc. 2020, 142, 9932–9937.
(One of the most cited articles from year 2020-2021)
Visible Light‐Induced Palladium‐Catalyzed Generation of Aryl Radicals from Aryl Triflates
Ratushnyy, M.; Kvasovs, N.; Sarkar, S.; Gevorgyan, V. Angew. Chem. Int. Ed. 2020, 59, 10316–10320.
Light-Induced Metal-Free Transformations of Unactivated Pyridotriazoles
Zhang, Z.; Yadagiri, D.; Gevorgyan, V. Chem. Sci. 2019, 10, 8399–8404.
Transition Metal- and Light-free Directed Amination of Remote Unactivated C(sp3)–H Bonds of Alcohols
Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
Kurandina, D.; Chuentragool, P.; Gevorgyan, V. Synthesis 2019, 51, 985–1005.
(Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue)
Catalysis by Visible Light Photoexcited Palladium Complexes
Chuentragool, P.; Kurandina, D.; Gevorgyan, V. Angew. Chem. Int. Ed. 2019, 58, 11586–11598.(Minireview)
Aliphatic Radical Relay Heck Reaction at Unactivated C(sp3)–H Sites of Alcohols.
A Mild Light-Induced Cleavage of S-O Bond of Aryl Sulfonate Esters Enables Efficient Sulfonylation of Vinylarenes
Ratushnyy, M.; Kamenova, M.; Gevorgyan, V. Chem. Sci. 2018, 9, 7193–7197.
General synthesis of pyrido[1,2-a]indoles via Pd-catalyzed cyclization of o-picolylbromoarenes
Chuentragool, P.; Li, Z.; Randle, K.; Mahchi, F.; Oshir, I.; Assaf, Sh.; Gevorgyan, V. J. Organometal. Chem. 2018, 867, 273–277. (Special Issue)
General, Mild, and Selective Method for Desaturation of Aliphatic Amines
Chuentragool, P.; Parasram, M.; Shi, Y.; Gevorgyan, V. J. Am. Chem. Soc. 2018, 140, 2465–2468.
Pd-Catalyzed Atom Transfer Radical Cyclization at Remote Unactivated C(sp3)-H Sites Enabled by Hydrogen Atom Transfer of Hybrid Vinyl Pd-Radical Intermediates
Ratushnyy, M.; Parasram, M.; Wang, Y.; Gevorgyan, V. Angew. Chem. Int. Ed. 2018, 57, 2712–2715.
Heck Reaction of Electronically Diverse Tertiary Alkyl Halides
Kurandina, D.; Rivas, M.; Radzhabov, M.; Gevorgyan, V. Org. Lett. 2018, 20, 357–360.
General, Auxiliary-Enabled Photoinduced Pd-Catalyzed Remote Desaturation of Aliphatic Alcohols
Visible Light-Induced Room Temperature Heck Reaction of Functionalized Alkyl Halides with Vinyl Arenes/Heteroarenes
Kurandina, D.; Parasram, M.; Gevorgyan, V. Angew. Chem. Int. Ed. 2017, 56, 14212–14216.
Visible Light-Induced Transition Metal-Catalyzed Transformations: Beyond Conventional Photosensitizers
Parasram, M.; Gevorgyan, V. Chem. Soc. Rev. 2017, 46, 6227–6240. (Tutorial Review)
Silicon-Tethered Strategies for C–H Functionalization Reactions
Parasram, M.; Gevorgyan, V. Acc. Chem. Res. 2017, 50, 2038–2053.
Synthesis of Active Hexafluoroisopropyl Benzoates through Hydrogen-Bond-Enabled Palladium(II)-Catalyzed C−H Alkoxycarbonylation Reaction
Wang, Y.; Gevorgyan, V. Angew. Chem. Int. Ed. 2017, 56, 3191–3195.
Coinage Metals in Organic Synthesis
Echavarren, A. M.; Jiao, N.; Gevorgyan, V. Chem. Soc. Rev. 2016, 45, 4445–4447. (Editorial)
Pd-Catalyzed C-H Alkylation of Arenes Using PyrDipSi, Transformable/Removable Silicon-Tethered Directing Group
Sarkar, D.; Gevorgyan, V. Chem. Eur. J. 2016, 22, 11201–11204.
Photoinduced Formation of Hybrid Aryl Pd-Radical Species Capable of 1,5-HAT: Selective Catalytic Oxidation of Silyl Ethers into Silyl Enol Ethers
Parasram, M.; Chuentragool, P.; Sarkar, D.; Gevorgyan, V. J. Am. Chem. Soc. 2016, 138, 6340–6343.
Rhodium Thiavinyl Carbenes from 1,2,3-Thiadiazoles Enable Modular Synthesis of Multisubstituted Thiophenes
Kurandina, D.; Gevorgyan, V. Org. Lett. 2016, 18, 1804–1807. 
Synthesis of Multisubstituted Arenes via PyrDipSi-Directed Unsymmetrical Iterative C–H Functionalizations
Sarkar, D.; Gulevich, A. V.; Melkonyan, F. S.; Gevorgyan, V. ACS. Catal. 2015, 5, 6792–6801.
Cu-Catalyzed Transannulation Reaction of Pyridotriazoles: General Access to Fused Polycyclic Indolizines
Shi, Y.; Gevorgyan, V. Chem. Commun. 2015, 51, 17166–17169.
Au-Catalyzed Pentannulation Reaction of Propargylic Esters Occurring at C(sp3)–H Site
General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed C-H Carboxylation
Wang, Y.; Gevorgyan, V. Angew. Chem. Int. Ed. 2015, 54, 2255–2259.
Synthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines
Kazem Shiroodi, R.; Rivera Vera, C.; Dudnik, A. S; Gevorgyan, V. Tetrahedron Lett. 2015, 56, 3251–3254.(Symposium-in-Print: Harry Wasserman)
Cu-Catalyzed Transannulation Reaction of Pyridotriazoles with Terminal Alkynes under Aerobic Conditions: Efficient Synthesis of Indolizines
Helan, V; Gulevich, A. V.; Gevorgyan, V. Chem. Sci. 2015, 6, 1928–1931.
Endo-Selective Pd-Catalyzed Silyl Methyl Heck Reaction
Parasram, M.; Iaroshenko, V. O.; Gevorgyan, V. J. Am. Chem. Soc. 2014, 136, 17926–17929.
(Highlighted in ACS Selects May 2016)
Rhodium-Catalyzed NH Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2-Picolylamines and Imidazo[1,5-a]pyridine
Shi, Y.; Gulevich, A. V.; Gevorgyan, V. Angew. Chem. Int. Ed. 2014, 53, 14191–14195.
1,2-Boryl Migration Empowers Regiodivergent Synthesis of Borylated Furans
Kazem Shiroodi, R.; Koleda, O.; Gevorgyan, V. J. Am. Chem. Soc. 2014, 136, 13146–13149.
C–H activation: The road less travelled to amination
Zatolochnaya, O. V.; Gevorgyan, V. Nat. Chem. 2014, 6, 661–633. (News & Views)
Carboxylate Switch between Hydro- and Carbopalladation Pathways in Regiodivergent Dimerization of Alkynes
Gold-Catalyzed 1,3-Transposition of Ynones
Kazem Shiroodi, R.; Soltani, M.; Gevorgyan, V. J. Am. Chem. Soc. 2014, 136, 9882–9885.
A New Reactivity Mode for the Diazo Group: Diastereoselective 1,3-Aminoalkylation Reaction of β-Amino-α-Diazoesters To Give Triazolines
Kuznetsov, A.; Gulevich, A.; Wink, D. J.; Gevorgyan, V. Angew. Chem. Int. Ed. 2014, 53, 9021–90125.
Conversion of 1-Alkenes into 1,4-Diols through an Auxiliary-mediated Formal Homoallylic C–H Oxidation
Ghavtadze, N; Melkonyan, F. S.; Gulevich, A.; Huang, C.; Gevorgyan, V. Nat. Chem. 2014, 6, 122–125. (Highlighted by C&EN and Nature Chemistry)
Brönsted Acid-Catalyzed One-Pot Synthesis of Indoles from o-Aminobenzyl Alcohols and Furans.
General and Practical Carboxyl-Group-Directed Remote C-H Oxygenation Reactions of Arenes
Wang, Y.; Gulevich, A.; Gevorgyan, V. Chem. Eur. J. 2013, 19, 15836–15840.
Intramolecular Transannulation of Alkynyl Triazoles via Alkyne–Carbene Metathesis Step: Access to Fused Pyrroles
Shi, Y.; Gevorgyan, V. Org. Lett. 2013, 15, 5394–5396.
Twofold Unsymmetrical C-H Functionalization of PyrDipSi-Substituted Arenes: A General Method for the Synthesis of Substituted meta-Halophenols
Synthesis of Fluoro- and Perfluoroalkyl Arenes via Palladium-Catalyzed [4 + 2] Benzannulation Reaction
Zatolochnaya, O. V.; Gevorgyan, V. Org. Lett. 2013, 15, 2562–2565.
Fused Heteroaromatic Dihydrosiloles: Synthesis and Double-Fold Modification
Kuznetsov, A.; Onishi, Y.; Inamoto, Y.; Gevorgyan, V. Org. Lett. 2013, 15, 2498–2501.
Metal-Catalyzed Double Migratory Cascade Reactions of Propargylic Esters and Phosphates
Kazem Shiroodi, R.; Gevorgyan, V. Chem. Soc. Rev. 2013, 42, 4991–5001. (Review)
Pyridine Group Assisted Addition of Diazo-Compounds to Imines in the 3-CC Reaction of 2-Aminopyridines, Aldehydes, and Diazo-Compounds
Gulevich, A. V.; Helan, V; Wink, D. J.; Gevorgyan, V. Org. Lett. 2013, 15, 956–959.
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles
Gulevich, A. V.; Dudnik, A. S.; Chernyak, N.; Gevorgyan, V. Chem. Rev. 2013, 113, 3084–3213. (Review)
Versatile Reactivity of Rhodium–Iminocarbenes Derived from N-Sulfonyl Triazoles
Gulevich, A. V.; Gevorgyan, V. Angew. Chem. Int. Ed. 2013, 52, 1371–1373. (Highlight)
Palladium-Catalyzed Carbonylative Cyclization/Arylation Cascade for 2-Aroylindolizine Synthesis
Li, Z.; Chernyak, D.; Gevorgyan, V. Org. Lett. 2012, 14, 6056–6059.
Pd-Catalyzed Modifiable Silanol-Directed Aromatic C-H Oxygenation
Huang, C.; Ghavtadze, N.; Godoi, B.; Gevorgyan, V. Chem. Eur. J. 2012, 18, 9789–9792.
General and Selective Head-to-Head Dimerization of Terminal Alkynes Proceeding via Hydropalladation Pathway
Beyond the Limits: Palladium-N-Heterocyclic Carbene-Based Catalytic System Enables Highly Efficient [4+2] Benzannulation Reactions
Zatolochnaya, O.; Galenko, A. V.; Gevorgyan, V. Adv. Synth. Catal. 2012, 354, 1149–1155.
Stereocontrolled 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay Toward Highly Functionalized 1,3-Dienes
Kazem Shiroodi, R.; Dudnik, A. S; Gevorgyan, V. J. Am. Chem. Soc. 2012, 134, 6928–6931.
Double-Fold C-H Oxygenation of Arenes Using PyrDipSi: a General and Efficient Traceless/Modifiable Silicon Tethered Directing Group
Gulevich, A. V.; Melkonyan, F. S.; Sarkar, D.; Gevorgyan, V. J. Am. Chem. Soc. 2012, 134, 5528–5531.
General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes
Kuznetsov, A.; Gevorgyan, V. Org. Lett. 2012, 14, 914–917.
One-Pot Arylative Epoxidation of Ketones by Employing Amphoteric Bromoperfluoroarenes
Li, Z.; Gevorgyan, V. Angew. Chem. Int. Ed. 2012, 51, 1225–1227.
Transition Metal Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems
Chattopadhyay, B.; Gevorgyan, V. Angew. Chem. Int. Ed. 2012, 51, 862–872. (Minireview)
Synthesis of Fused Heterocycles via Pd-catalyzed Multiple Aromatic C-H Activation Reactions
Gulevich, A.V., Gevorgyan, V. Chem. Heterocycl. Compd. 2012, 2012, 48, 17–20. (Highlight)
Organocopper-mediated two-component SN2′-substitution cascade towards N-fused heterocycles
Chernyak, D.; Gevorgyan, V. Chem. Heterocycl. Compd. 2011, 47, 1516–1526.
Synthesis of Catechols from Phenols via Pd-Catalyzed Silanol-Directed C–H Oxygenation
Huang, C.; Ghavtadze, N.; Chattopadhyay, B.; Gevorgyan, V. J. Am. Chem. Soc. 2011, 133, 17630–17633.
Palladium-catalyzed Highly Regioselective C-3 Arylation of Imidazo[1,5-a]pyridine
Huang, C; Giokaris, A; Gevorgyan, V. Chem. Lett. 2011, 40, 1053–1054. (Special Issue)
Silanol: A Traceless Directing Group for Pd-Catalyzed o-Alkenylation of Phenols
Huang, C.; Chattopadhyay, B.; Gevorgyan, V. J. Am. Chem. Soc. 2011, 133, 12406–12409.
Rh-Catalyzed Transannulation of N-Tosyl-1,2,3-Triazoles with Terminal Alkynes
Chattopadhyay, Buddhadeb; Gevorgyan, V. Org. Lett. 2011, 13, 3746–3749.
The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes
Huang, C.; Chernyak, N.; Dudnik, A. S.; Gevorgyan, V. Adv. Synth. Catal. 2011, 353, 1285–1305.
Double Duty for Cyanogen Bromide in a Cascade Synthesis of Cyanoepoxides
Li, Z.; Gevorgyan, V. Angew. Chem. Int. Ed. 2011, 50, 2808–2810.
Palladium-Catalyzed Carbocyclization of Alkynyl Ketones Proceeding through a Carbopalladation Pathway
Chernyak, N.; Gorelsky, S. I.; Gevorgyan, V. Angew. Chem. Int. Ed. 2011, 50, 2342–2345.
Cascade carbopalladation-annulation approach toward polycylic derivatives of indole and indolizine
Chernyak,N.; Tilly, D.; Li, Z.; Gevorgyan, V. ARKIVOC 2011 (V), 76–91. (Special Issue)
Transition Metal-Catalyzed Synthesis of Fused Five-Membered Aromatic Heterocycles
Transition Metal-Catalyzed Synthesis of Monocyclic Five-Membered Aromatic Heterocycles
On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped Propargylpyridines
Xia, Y; Dudnik, A. S., Li, Y.; Gevorgyan, V. Org. Lett. 2010, 12, 5538–5541.
Palladium-Catalyzed Intramolecular Carbopalladation/Cyclization Cascade: Access to Polycyclic N-Fused Heterocycles
Chernyak, D; Gevorgyan, V. Org. Lett. 2010, 12, 5558–5560.
Copper-, Silver-, and Gold Catalyzed Migratory Cycloisomerization Leading to Heterocyclic Five-Membered Rings
Dudnik, A; Chernyak, N; Gevorgyan, V. Aldrichim. Acta. 2010, 43, 37–46. (Review)
A General Strategy Toward Aromatic 1,2-Ambiphilic Synthons: Palladium-Catalyzed ortho-Halogenation of PyDipSi-Arenes
Dudnik, A.; Chernyak, N.; Huang, C.; Gevorgyan, V. Angew. Chem. Int. Ed. 2010, 49, 8729–8732.
Two-Component Approach Toward a Fully Substituted N-Fused Pyrrole Ring
Chernyak, D.; Skontos, C.; Gevorgyan, V. Org. Lett. 2010, 12, 3242–3245.
PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C-H Acyloxylation of Arenes
Chernyak, N.; Dudnik, A.; Huang, C.; Gevorgyan, V. J. Am. Chem. Soc. 2010, 132, 8270–8272.
Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans
Dudnik, A.; Xia, Y.; Li, Y.; Gevorgyan, V. J. Am. Chem. Soc. 2010, 132, 7645–7655.
Synthesis of Unsymmetrical o-Biphenols and o-Binaphthols via Silicon-Tethered Pd-Catalyzed C-H Arylation
Huang, C.; Gevorgyan, V. Org. Lett. 2010, 12, 2442–2445.
Fused Tetrazoles as Azide Surrogates in Click Reaction: Efficient Synthesis of N-Heterocycle Substituted 1,2,3-Triazoles
Chattopadhyay, B.; Rivera Vera, C.; Chuprakov, S.; Gevorgyan, V. Org. Lett. 2010, 12, 2166–2169.
Efficient and General Synthesis of 3-Aminoindolines and 3-Aminoinoles via Copper-Catalyzed Three-Component Coupling Reaction
Chernyak, D.; Chernyak, N.; Gevorgyan, V. Adv. Synth. Catal. 2010, 352, 961–966.
Formal Inverse Sonogashira Reaction: Direct Alkynylation of Arenes and Heterocycles with Alkynyl Halides
Dudnik, A.; Gevorgyan, V. Angew. Chem. Int. Ed. 2010, 49, 2096–2098. (Highlight)
General and Efficient Copper-Catalyzed Three-Component Coupling Reaction Towards Imidazoheterocycles: One-Pot Synthesis of Alpidem and Zolpidem
Chernyak, N.; Gevorgyan, V. Angew. Chem. Int. Ed. 2010, 49, 2743–2746.
Pd-catalyzed cascade carbopalladation-annulation reaction of 3-(2-iodobenzyl)-indoles into fused 6/5/7/6- and 6/5/5/6- heterocyclic systems
Chernyak, N.; Tilly, D.; Li, Z.; Gevorgyan, V. Chem. Commun. 2010, 46,150–152. (Special Issue)
TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines
Huang, C.; Gevorgyan, V. J. Am. Chem. Soc. 2009, 131, 10844–10845.
Synthesis of Fluorenes via the Palladium-Catalyzed 5-exo-dig Annulation of o-Alkynylbiaryls
Chernyak, N.; Gevorgyan, V. Adv. Synth. Catal. 2009, 351, 1101–1114. (Special Issue)
Gold(I)-catalyzed double migration cascades toward (1E, 3E)-dienes and naphthalenes
Dudnik, A. S.; Schwier, T.; Gevorgyan, V. Tetrahedron. 2009, 65, 1859–1870. (Symposium-In-Print)
Gold(I)-Catalyzed Synthesis of (1E,3E)-dienes from propargylic esters
Dudnik, A. S.; Schwier, T.; Gevorgyan, V. J. Organomet. Chem. 2009, 694, 482–485. (Special Issue on Gold Catalysis)
Sila-Morita-Baylis-Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem
Trofimov, A.; Gevorgyan, V. Org. Lett. 2009, 11, 253–255.
Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles
Dual Role of Alkynyl Halides in One-Step Synthesis Of Alkynyl Epoxides
Trofimov, A.; Chernyak N.; Gevorgyan, V. J. Am. Chem. Soc. 2008, 130, 13538–13539.
Mechanistic Insights into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity
Xia Y.; Dudnik, A. S.; Gevorgyan, V. ; Li, Y. J. Am. Chem. Soc. 2008, 130, 6940-6941.
Low Temperature Organocopper-Mediated Two-Component Cross Coupling/Cycloisomerization Approach Toward N-Fused Heterocycles
Chernyak, D.; Gadamsetty, S.; Gevorgyan, V. Org. Lett. 2008, 10, 2307-2310.
Multisubstituted N-Fused heterocycles via transtion metal-catalyzed cycloisomerization protocols
Seregin, I.; Schammel, A.; Gevorgyan, V. Tetrahedron. 2008, 64, 6876-6883. (Symposium-In-Print)
Exclusive 5-exo-dig Hydroarylation of o-Alkynyl Biaryls Proceeding via C−H Activation Pathway
N. Chernyak, V. Gevorgyan, J. Am. Chem. Soc. 2008, 130, 5636-5637.
Gold-Catalyzed Double Migration-Benzannulation Cascade toward Naphthalenes
A. S. Dudnik, T. Schwier, V. Gevorgyan, Org. Lett.2008, 10, 1465-1468.
Metal-Catalyzed 1,2-Shift of Diverse Migrating Groups in Allenyl Systems as a New Paradigm toward Densely Functionalized Heterocycles
Sila Morita-Baylis-Hillman Reaction of Cyclopropenes
S. Chuprakov, D. Malyshev, A. Trofimov, V. Gevorgyan, J. Am. Chem. Soc. 2007, 129, 14868 – 14869.
Highly Diastereo- and Regioselective Transition Metal-Catalyzed Additions of Metal Hydrides and Bimetallic Species to Cyclopropenes: Easy Access to Multisubstituted Cyclopropanes
A. Trofimov, M. Rubina, M. Rubin, V. Gevorgyan, J. Org. Chem. 2007, 72, 8910-8920.
Regiodivergent Metal-Catalyzed Rearrangement of 3-Iminocyclopropenes into N-Fused Heterocycles
S. Chuprakov, V. Gevorgyan, Org. Lett. 2007, 9, 4463-4466.
Mechanistically Diverse Copper-, Silver-, and Gold-Catalyzed Acyloxy and Phosphatyloxy Migrations: Efficient Synthesis of Heterocycles via Cascade Migration/Cycloisomerization Approach
Base- and Ligand-free Room-Temperature Synthesis of N-Fused Heteroaromatic Compounds via the Transition Metal-Catalyzed Cycloisomerization Protocol
I. V. Seregin, A. Schammel, V. Gevorgyan, Org. Lett. 2007, 9, 3433-3436.
Transition Metal Chemistry of Cyclopropenes and Cyclopropanes
M. Rubin, M. Rubina, V. Gevorgyan, Chem. Rev. 2007, 107, 3117-3179. (Review)
Direct Palladium-Catalyzed Alkynylation of N-Fused Heterocycles
I. V. Seregin, V. Ryabova, V. Gevorgyan, J. Am. Chem. Soc. 2007, 129, 7742-7743.
Metal-Catalyzed [1,2]-Alkyl Shift in Allenyl Ketones: Synthesis of Multisubstituted Furans
A. S. Dudnik, V. Gevorgyan, Angew. Chem. Int. Ed. 2007, 46, 5195-5197.
Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles
S. Chuprakov, F. Hwang, V. Gevorgyan, Angew. Chem. Int. Ed. 2007, 46, 4757-4759.
Direct Pd-Catalyzed Arylation of 1,2,3-Triazoles
S. Chuprakov, N. Chernyak, A. S. Dudnik, V. Gevorgyan, Org Lett. 2007, 9, 2333-2336.
Direct transition metal-catalyzed functionalization of heteroaromatic compounds
I. V. Seregin, V. Gevorgyan, Chem. Soc. Rev. 2007, 36, 1173-1193. (Review)
1,2-Sulfur Migrations
A. W. Sromek, V. Gevorgyan, Top. Curr. Chem. 2007, 274, 77-124. (Review)
Gold-Catalyzed 1,2-Migration of Silicon, Tin, and Germanium en Route to C-2 Substituted Fused Pyrrole-Containing Heterocycles
Seregin, I. V.; Gevorgyan, V. J. Am. Chem. Soc. 2006, 128, 12050-12051.
Chemodivergent Transformations of Alkynyl Imines
A.W. Sromek, A.L. Rheingold, D. J. Wink, V. Gevorgyan, Synlett 2006, 14, 2325-2329. (Cluster Article)
Solvent dependent photocyclization and photophysics of some 2-ethynylbiphenyls
Dramatic Acceleration of the Pd-Catalyzed [4+2] Benzannulation Reaction of Enynes and Diynes in the Presence of Lewis Acids and Bases: Expanded Scope and New Mechanistic Insights
M.Rubina, M.Conley V. Gevorgyan, J. Am. Chem. Soc. 2006, 128, 5818-5827.
Recent Advances in Cyclopropene Chemistry
M. Rubin, M. Rubina, V. Gevorgyan, Synthesis 2006, 1221-1245. (Review)
Ring-Closing Photoisomerization of Some 2,6-Diarylstyrenes
Competitive 1,2- and 1,5-Hydrogen Shifts Following 2-Vinylbiphenyl Photocyclization
F. D. Lewis, M. C. Sajimon, X. Zuo, M. Rubin, V. Gevorgyan, J. Org. Chem. 2005, 70, 10447-10452.
Trans- and Cis-Selective Lewis Acid Catalyzed Hydrogermylation of Alkynes
Schwier, T.; Gevorgyan, V. Org. Lett. 2005, 7, 5191-5194.
Direct Palladium-Catalyzed Arylation of Cyclopropenes
S. Chuprakov, M. Rubin, V. Gevorgyan, J. Am. Chem. Soc. 2005, 127, 3714-3715.
1,2-Halogen Migration in Haloallenyl Ketones: Regiodivergent Synthesis of Halofurans
A.W. Sromek, M. Rubina, V. Gevorgyan, J. Am. Chem. Soc. 2005, 127, 10500-10501.
Can Polarization of Triple Bond in Tolanes Be Deduced from 13C NMR Shifts? Re-Evaluation of Factors Affecting Regiochemistry of the Palladium-Catalyzed Hydrostannation of Alkynes
M. Rubin, A. Trofimov, V. Gevorgyan, J. Am. Chem. Soc. 2005, 127, 10243-10249.
Selective Partial Reduction of Various Heteroaromatic Compounds with Bridgehead Nitrogen via Birch Reduction Protocol
J. T. Kim, V. Gevorgyan, J. Org. Chem. 2005, 70, 2054-2059.
Direct Electrophilic Silylation of Terminal Alkynes
Highly Diastereoselective Approach toward (+/-)-Tetraponerine T6 and Analogues via the Double Cycloisomerization-Reduction of Bis-alkynylpyrimidines
J. T. Kim, J. Butt, V. Gevorgyan, J. Org. Chem. 2004, 69, 5638-5645.
B(C6F5)3-Catalyzed Allylation of Propargyl Acetates with Allylsilanes
Schwier, T.; Rubin, M.; Gevorgyan, V. Org. Lett. 2004, 6, 1999-2001.
A Novel 1,2-Migration of Acyloxy, Phosphatyloxy, and Sulfonyloxy Groups in Allenes: Efficient Synthesis of Tri- and Tetrasubstituted Furans
Sromek, A.; Kel’in, A.; Gevorgyan, V. Angew. Chem. Int. Ed. 2004, 43, 2280-2282.
Simple Large-Scale Preparation of 3,3-Disubstituted Cyclopropenes: Easy Access to Stereodefined Cyclopropylmetals via Transition Metal-Catalyzed Hydrometallation
M. Rubin, V. Gevorgyan, Synthesis 2004, 796-800.(Practical Synthetic Procedure)
Palladium-Catalyzed Arylation and Heteroarylation of Indolizines
Park, C.; Ryabova, V.; Seregin, I.; Sromek, A.; Gevorgyan, V. Org. Lett. 2004, 6, 1159-1162.
Cyclopropylstannanes: Synthesis and Applications
M. Rubina, V. Gevorgyan, Tetrahedron 2004, 60, 3129-3159.(Review)
Catalytic Enantioselective Hydrostannation of Cyclopropenes
M. Rubina, M. Rubin, V. Gevorgyan, J. Am. Chem. Soc. 2004, 126, 3688-3689.
Reduction of Carbonyl Function to a Methyl Group
G. B. Bajracharya, T. Nogami, T. Jin, K. Matsuda, V. Gevorgyan, Y. Yamamoto, Synthesis 2004, 308-311.(Practical Synthetic Procedure)
Direct Electrophilic Silylation of Terminal Alkynes
New Advances in Selected Transition Metal-Catalyzed Annulations
M. Rubin, A. W. Sromek, V. Gevorgyan, Synlett 2003, 2265-2291. (Account)
Highly Regiocontrolled Pd-Catalyzed Cross-Coupling Reaction of Terminal Alkynes and Allenylphosphine Oxides
M. Rubin, J. Markov, S. Chuprakov, D. J. Wink, V. Gevorgyan, J. Org. Chem. 2003, 68, 6251.
Catalytic Enantioselective Hydroboration of Cyclopropenes
M. Rubina, M. Rubin, V. Gevorgyan, J. Am. Chem. Soc. 2003, 125, 7198-7199.
1,2-Migration of the Thio Group in Allenyl Sulfides: Efficient Synthesis of 3-Thio-Substituted Furans and Pyrroles
J. T. Kim, A. V. Kel’in, and V. Gevorgyan, Angew. Chem. Int. Ed. 2003, 42, 98.
Double Cycloisomerization as a Novel and Expeditious Route to Tricyclic Heteroaromatic Compounds: Short and Highly Diastereoselective Synthesis of Tetraponerine T6
J. T. Kim and V. Gevorgyan, Org. Lett. 2002, 4, 4697.
IV.5. Alkynyl Substitution via Alkynylpalladation-Reductive Elimination
IV.2.6. Carbopalladation of Alkynes Followed by Trapping with Electrophiles
Symmetry-Enforced Conformational Control of Photochemical Reactivity in 2-Vinyl-1,3-terphenyl
F. D. Lewis, X. Zuo, V. Gevorgyan, and M. Rubin, J. Am. Chem. Soc. 2002, 124, 13664-13665.
Transition Metal-Catalyzed Hydro-, Sila-, and Stannastannation of Cyclopropenes: Stereo- and Regioselective Approach toward Multisubstituted Cyclopropyl Synthons
M. Rubina, M. Rubin, and V. Gevorgyan, J. Am. Chem. Soc. 2002, 124, 11566-11567.
Highly Efficient B(C6F5)3-Catalyzed Hydrosilylation of Olefins
M. Rubin, T. Schwier, and V. Gevorgyan, Org. Chem. 2002, 67, 1936.
Efficient Synthesis of 2-Mono- and 2,5-Disubstituted Furans via the CuI-Catalyzed Cycloisomerization of Alkynyl Ketones
A. V. Kel’in and V. Gevorgyan, J. Org. Chem. 2002, 67, 95.
Can Agostic Interaction Affect Regiochemistry of Carbopalladation? Reverse Regioselectivity in the Palladium-Catalyzed Dimerization of Aryl Acetylenes
M. Rubina and V. Gevorgyan, J. Am. Chem. Soc. 2001, 123, 11107.
B(C6F5)3 – Catalyzed Allylation of Secondary Benzyl Acetates with Allylsilanes
M. Rubin and V. Gevorgyan, Org. Lett. 2001, 3, 2705.
A Novel Cu-Assisted Cycloisomerization of Alkynyl Imines: Efficient Synthesis of Pyrroles and Pyrrole-Containing Heterocycles
A. V. Kel’in, A. W. Sromek, and V. Gevorgyan, J. Am. Chem. Soc. 2001, 123, 2074.
Lewis Acid-Mediated Intramolecular Addition of Silyl Enol Ethers to Internal Unactivated Alkynes
K. Imamura, E. Yoshikawa, V. Gevorgyan, T. Sudo, N. Asao, Y. Yamamoto, Can. J. Chem. 2001, 79, 1624.
Palladium Catalyzed Highly Chemo- and Regioselective Formal [2+2+2] Sequential Cycloaddition of Alkynes: a Renaissance of the Well Known Trimerization Reaction?
Synthesis of Cyclophanes via an Intermolecular Pd-Catalyzed Enyne-Diyne Cross-Benzannulation Approach
V. Gevorgyan, N. Tsuboya, Y. Yamamoto, J. Org. Chem. 2001, 66, 2734.
A Direct Reduction of Aliphatic Aldehyde, Acyl Chloride, Ester, and Carboxylic Functions into a Methyl Group
V. Gevorgyan, M. Rubin, J.-X. Liu, Y. Yamamoto, J. Org. Chem. 2001, 66, 1672.
A Novel B(C6F5)3-Catalyzed Reduction of Alcohols and Cleavage of Aryl and Alkyl Ethers with Hydrosilanes
V. Gevorgyan, M. Rubin, S. Benson, J.-X. Liu, Y. Yamamoto, J. Org. Chem. 2000, 65, 6179.
HI-Mediated Cyclization of o-Alkynylstyrenes
S. Saito, M. Homma, V. Gevorgyan, Y. Yamamoto, Chem. Lett. 2000, 722.
Palladium-Catalyzed cross-Benzannulation of Aminoenynes with Diynes. Highly Regioselective Synthesis of Polysubstituted Anilines
S. Saito, N. Uchiyama, V. Gevorgyan, Y. Yamamoto, J. Org. Chem. 2000, 65, 4338.
Palladium-Catalyzed [2+2+1] Cyclotrimerization of Alkynes: Selective Synthesis of Fulvenes
U. Radhakrishnan, V. Gevorgyan, and Y. Yamamoto, Tetrahedron Lett. 2000, 41, 1971. 
Effective Synthesis of Aryl Ethers and Coumaranones Employing the Palladium-Catalyzed Enyne-Diyne [4+2] Cycloaddition Protocol
V. Gevorgyan, K. Tando, N. Uchiyama, and Y. Yamamoto, J. Org. Chem. 2000, 65, 568.
A Novel Reduction of Alcohols and Ethers with a HSiEt3/Catalytic B(C6F5)3 System
V. Gevorgyan, J.-X. Liu, M. Rubin, S. Benson, Y. Yamamoto, Tetrahedron Lett. 1999, 40, 8919.
Palladium Catalyzed [4+2] Cross-Benzannulation Reaction of Conjugated Enynes with Diynes and Triynes
Palladium-Catalyzed Enyne-Yne [4+2] Benzannulation as a New and General Approach to Polysubstituted Benzenes
V. Gevorgyan and Y. Yamamoto, J. Organomet. Chem. 1999, 576, 232. (review)
Synthesis of Indenols and Indanones via Catalytic Cyclic Vinylpalladation of Aromatic Aldehydes
V. Gevorgyan, L. G. Quan, and Y. Yamamoto, Tetrahedron Lett. 1999, 40, 4089.
First Addition of Silyl Enol Ethers to Internal Unactivated Alkynes
K. Imamura, E. Yoshikawa, V. Gevorgyan, Y. Yamamoto, Tetrahedron Lett. 1999, 40, 4081.
Lewis Acid Catalyzed Highly Regio- and Stereocontrolled trans-Hydrosilylation of Alkynes and Allenes
T. Sudo, N. Asao, V. Gevorgyan, Y. Yamamoto, J. Org. Chem. 1999, 64, 2494.
Intramolecular Nucleophilic Addition of Vinylpalladiums to Aryl Ketones
Long Guo Quan, Vladimir Gevorgyan, Yoshinori Yamamoto, J. Am. Chem. Soc. 1999, 121, 3545.
An Efficient Route to 2,6-Disubstituted Styrenes via the Palladium-Catalyzed [4 + 2] Cyclodimerization of Conjugated Enynes
V. Gevorgyan, K. Tando, N. Uchiyama, Y. Yamamoto, J. Org. Chem. 1998, 63, 7022.
First Exclusive endo-dig Carbocyclization: HfCl4-Catalyzed Intramolecular Allylsilylation of Alkynes
K. Imamura, E. Yoshikawa, V. Gevorgyan, Y. Yamamoto. J. Am. Chem. Soc.1998, 120, 5339.
Regiospecific Synthesis of Polysubstituted Phenols via the Palladium-Catalyzed Enyne-Diyne [4+2] Cross-Benzannulation
V. Gevorgyan, L.G. Quan, Y. Yamamoto. J. Org. Chem. 1998, 63, 1244.
Synthesis of Polyether Exomethylene Paracyclophanes via an Intramolecular Pd-Catalyzed Bis-Enyne Benzannulation Protocol
D. Weibel, V. Gevorgyan, Y. Yamamoto.J. Org. Chem. 1998, 63,1217-1220.
Hydrostannation of C-C multiple bonds with Bu3SnH prepared in situ from Bu3SnCl and Et3SiH in the presence of Lewis acid catalysts
V. Gevorgyan, J.-X. Liu, Y. Yamamoto Chem. Commun. 1998, 37.
A novel Route to Pentacoordinated Organylsilanes and -Germanes
The First Chemo- and Regiospecific Palladium-Catalyzed Enyne-Diyne [4+2] Intermolecular Cross-Benzannulation: An Effective Route to Polysubstituted Benzenes
V. Gevorgyan, N. Sadayori, Y. Yamamoto. Tetrahedron Lett.1997, 38, 8603.
First Intermolecular Regiospecific Palladium Catalyzed Enyne-Diyne [4+2] Cross-Benzannulation Reaction
V. Gevorgyan, A. Takeda, Y.Yamamoto. J. Am. Chem. Soc. 1997, 119, 11313.
Addition of Tris(trimethylsilyl)germyl Radicals to Unsaturated Compounds. An EPR and Product Study
Intramolecular Reaction of -Alkoxyallylstannane with Aldehyde: Origin of the Stereoselectivities
I. Kadota, M. Kawada, V. Gevorgyan, Y. Yamamoto, J. Org. Chem. 1997, 62, 7439.
Strained 6-Membered Cyclic Cumulenes as Intermediates in Dehydro Diels-Alder Cycloadditions
V. Gevorgyan, and Y. Yamamoto, Chemtracts 1997, 10, 646.
Lewis Acid-Catalyzed trans-Allylsilylation of Unactivated Alkynes
E. Yoshikawa, V. Gevorgyan, N. Asao, and Y. Yamamoto, J. Am. Chem. Soc. 1997, 119, 6781.
Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes
Regioselective Synthesis of 1,3,5-Unsymmetrically Substituted Benzenes via the Palladium Catalyzed Cyclotrimerization of 1,3-Diynes
Takeda, A. Ohno, I. Kadota, V. Gevorgyan, and Y. Yamamoto, J. Am. Chem. Soc. 1997, 119, 4547.
Highly Regiocontrolled and Efficient Synthesis of Vinyl- and Allylstannanes via Lewis Acids and Pd-Catalyzed Hydrostannation of Allenes: Scope and Limitations
V. Gevorgyan,J-X. Liu, and Y. Yamamoto, J. Org. Chem. 1997, 62, 2963.
Reactions of Dihydrofurylsilanes With O- and N-Nucleophiles
E. Lukevics, V. Gevorgyan, L. Borisova, Khim. Geterotsikl. Soedin. 1997, 186, (Russ.)
Organosilatranes From Reaction of Tetraorganylsilanes with Triethanolamine
V. Gevorgyan, L. Borisova, and E. Lukevics, J. Organomet. Chem. 1997, 527, 295.
A New Palladium Catalysed Benzannulation of Conjugated Enynes
Palladium Catalysed Addition of Certain Activated Methynes to Conjugated Enynes
M. M. Salter, V. Gevorgyan, S. Saito, and Y. Yamamoto, Chem. Commun. 1996, 17.