-
Nickel-Catalyzed Branched Hydroalkylation of Alkenes with Diazo Compounds
Nikita Kvasovs#, Valeria Iziumchenko#, Alistair J. Sterling, Vladimir Gevorgyan*
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Illuminating Palladium Catalysis
Kelvin Pak Shing Cheung, Vladimir Gevorgyan*
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Photoinduced Pd-Catalyzed Direct Sulfonylation of Allylic C–H Bonds
Kallol Mukherjee, Kelvin Pak Shing Cheung, Vladimir Gevorgyan*
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General Regio- and Diastereoselective Allylic C–H Oxygenation of Internal Alkenes
Kyohei Yamada, Kelvin Pak Shing Cheung, Vladimir Gevorgyan*
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Visible Light-Induced Reactions of Diazo Compounds and Their Precursors
Ziyan Zhang, Vladimir Gevorgyan*
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Recent Advances in Visible Light Induced Palladium Catalysis
Sumon Sarkar, Kelvin Pak Shing Cheung, Vladimir Gevorgyan*
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Escape from Hydrofunctionalization: Palladium Hydride-Enabled Difunctionalization of Conjugated Dienes and Enynes
Ziyan Zhang, Vladimir Gevorgyan*
Angew. Chem., Int. Ed. 2023, 62, e202311848
(Hot Paper)
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One-Pot Formal Carboradiofluorination of Alkenes: A Toolkit for Positron Emission Tomography Imaging Probe Development
Mónica Rivas#, Sashi Debnath#, Sachin Giri, Yusuf Noffel, Xiankai Sun*, Vladimir Gevorgyan*
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Merging of Light/Dark Palladium Catalytic Cycles Enables Multicomponent Tandem Alkyl Heck/Tsuji–Trost Homologative Amination Reaction toward Allylic Amines
Nikita Kvasovs, Jian Fang, Fedor Kliuev, Vladimir Gevorgyan*
J. Am. Chem. Soc. 2023, 145, 18497-18505
(In Top 10 Most Read Articles, Sep 2023)
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Enhanced Excited State Hydricity of Pd–H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes
Sumon Sarkar, Soumen Ghosh, Daria Kurandina, Yusuf Noffel, Vladimir Gevorgyan*
J. Am. Chem. Soc. 2023, 145, 12224–12232
(In Top 20 Most Read Articles, June 2023)
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Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis
Valeria Iziumchenko, Vladimir Gevorgyan*
(invited review)
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Advances in Selected Heterocyclization Methods
Mónica Rivas, Vladimir Gevorgyan*
(Invited Account)
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Targeting lipid-protein interaction to treat Syk-mediated acute myeloid leukemia
Indira Singaram, Ashutosh Sharma, Shashank Pant, Muyun Lihan, Mi-Jeong Park, Melissa Pergande, Pawanthi Buwaneka, Yusi Hu, Nadim Mahmud, You-Me Kim, Stephanie Cologna, Vladimir Gevorgyan, Irum Khan, Emad Tajkhorshid & Wonhwa Cho
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Asymmetric Intermolecular Allylic C–H Amination of Alkenes With Aliphatic Amines
Kelvin Pak Shing Cheung, Jian Fang, Kallol Mukherjee, Andranik Mihranyan, Vladimir Gevorgyan*
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Palladium Hydride-Enabled Hydroalkenylation of Strained Molecules
Ziyan Zhang, Vladimir Gevorgyan*
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General and selective metal-free radical α-C–H borylation of aliphatic amines
Sumon Sarkar, Sidhant Wagulde, Xiangqing Jia, Vladimir Gevorgyan*
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Recent advances in visible light-induced C(sp3)–N bond formation
Mónica Rivas, Vitalii Palchykov, Xiangqing Jia, Vladimir Gevorgyan*
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Accessing Illusive E Isomers of α-Ester Hydrazones via Visible-Light-Induced Pd-Catalyzed Heck-Type Alkylation
Nikita Kvasovs, Vladimir Gevorgyan*
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Visible-Light-Induced Brønsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones
Ziyan Zhang, Nikita Kvasovs, Anastasiia Dubrovina, Vladimir Gevorgyan*
Angew. Chem., Int. Ed. 2022, 61, e202110924
(Top Downloaded Article)
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Visible Light-Induced Transition Metal Catalysis
Kelvin Pak Shing Cheung, Sumon Sarkar, Vladimir Gevorgyan*
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Three-Component Visible-Light-Induced Palladium-Catalyzed 1,2-Alkyl Carbamoylation/Cyanation of Alkenes
Xiangqing Jia, Ziyan Zhang, Vladimir Gevorgyan*
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Visible Light-Induced Pd-Catalyzed Alkyl-Heck Reaction of Oximes
Nikita Kvasovs, Valeriia Iziumchenko, Vitalii Palchykov, Vladimir Gevorgyan*
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Contemporary Methods for Generation of Aryl Radicals
Nikita Kvasovs, Vladimir Gevorgyan*
Chem. Soc. Rev. 2021, 50, 2244–2259
(Tutorial Review)
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C–H Functionalization Reactions Enabled by Hydrogen Atom Transfer to Carbon-Centered Radicals
Sumon Sarkar#, Kelvin Pak Shing Cheung#, Vladimir Gevorgyan*
Chem. Sci. 2020, 11, 12974–12993
(Perspective)
(Most popular 2019-2020 review articles), (Most popular 2019-2020 organic chemistry articles)
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Co-Catalyzed Transannulation of Pyridotriazoles with Isothiocyanates and Xanthate Esters
Ziyan Zhang, Vladimir Gevorgyan*
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Denitrogenative Transformations of Pyridotriazoles and Related Compounds: Synthesis of N-Containing Heterocyclic Compounds and Beyond
Yadagiri Dongari, Mónica Rivas, Vladimir Gevorgyan*
J. Org. Chem. 2020, 85, 11030–11046
(Perspective)
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Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and Beyond
Kelvin Pak Shing Cheung, Daria Kurandina, Tetsuji Yata, Vladimir Gevorgyan*J. Am. Chem. Soc. 2020, 142, 9932–9937
(One of the most cited articles from year 2020-2021)
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Visible Light‐Induced Palladium‐Catalyzed Generation of Aryl Radicals from Aryl Triflates
Maxim Ratushnyy, Nikita Kvasovs, Sumon Sarkar, Vladimir Gevorgyan*
Angew. Chem. Int. Ed. 2020, 59, 10316–10320.
(Hot Paper)
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Light-Induced Metal-Free Transformations of Unactivated Pyridotriazoles
Ziyan Zhang#, Yadagiri Dongari#, Vladimir Gevorgyan*
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Transition Metal- and Light-free Directed Amination of Remote Unactivated C(sp3)–H Bonds of Alcohols
Daria Kurandina, Dongari Yadagiri, Mónica Rivas, Aleksei Kavun, Padon Chuentragool, Keiichi Hayama, Vladimir Gevorgyan*
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Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
Daria Kurandina#, Padon Chuentragool#, Vladimir Gevorgyan*
(Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue)
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Catalysis by Visible Light Photoexcited Palladium Complexes
Padon Chuentragool, Daria Kurandina, Vladimir Gevorgyan*
Angew. Chem. Int. Ed. 2019, 58, 11586–11598
(Mini Review)
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A Mild Light-Induced Cleavage of S-O Bond of Aryl Sulfonate Esters Enables Efficient Sulfonylation of Vinylarenes
Maxim Ratushnyy, Monika Kamenova, Vladimir Gevorgyan*
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General synthesis of pyrido[1,2-a]indoles via Pd-catalyzed cyclization of o-picolylbromoarenes
Padon Chuentragool, Zhou Li, Katrina Randle, Faraj Mahchi, Ishmael Ochir, Shadi Assaf, Vladimir Gevorgyan*
J. Organometal. Chem. 2018, 867, 273–277
(Special Issue)
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General, Mild, and Selective Method for Desaturation of Aliphatic Amines
Padon Chuentragool, Marvin Parasram, Yi Shi, Vladimir Gevorgyan*
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Pd-Catalyzed Atom Transfer Radical Cyclization at Remote Unactivated C(sp3)-H Sites Enabled by Hydrogen Atom Transfer of Hybrid Vinyl Pd-Radical Intermediates
Maxim Ratushnyy, Marvin Parasram, Yang Wang, Vladmir Gevorgyan*
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Heck Reaction of Electronically Diverse Tertiary Alkyl Halides
Daria Kurandina, Mónica Rivas, Maxim Radzhabov, Vladimir Gevorgyan*
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General, Auxiliary-Enabled Photoinduced Pd-Catalyzed Remote Desaturation of Aliphatic Alcohols
Marvin Parasram, Padon Chuentragool, Yang Wang, Yi Shi, Vladimir Gevorgyan*
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Visible Light-Induced Room Temperature Heck Reaction of Functionalized Alkyl Halides with Vinyl Arenes/Heteroarenes
Daria Kurandina, Marvin Parasram, Vladimir Gevorgyan*
-
Visible Light-Induced Transition Metal-Catalyzed Transformations: Beyond Conventional Photosensitizers
Marvin Parasram, Vladimir Gevorgyan*
Chem. Soc. Rev. 2017, 46, 6227–6240
(Tutorial Review)
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Silicon-Tethered Strategies for C–H Functionalization Reactions
Marvin Parasram, Vladimir Gevorgyan*
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Synthesis of Active Hexafluoroisopropyl Benzoates through Hydrogen-Bond-Enabled Palladium(II)-Catalyzed C−H Alkoxycarbonylation Reaction
Yang Wang, Vladimir Gevorgyan*
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Coinage Metals in Organic Synthesis
Antonio M. Echavarren*, Ning Jiao*, Vladimir Gevorgyan*
Chem. Soc. Rev. 2016, 45, 4445–4447
(Editorial)
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Pd-Catalyzed C-H Alkylation of Arenes Using PyrDipSi, Transformable/Removable Silicon-Tethered Directing Group
Dhruba Sarkar, Vladimir Gevorgyan*
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Photoinduced Formation of Hybrid Aryl Pd-Radical Species Capable of 1,5-HAT: Selective Catalytic Oxidation of Silyl Ethers into Silyl Enol Ethers
Marvin Parasram, Padon Chuentragool, Dhruba Sarkar, Vladimir Gevorgyan*
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Rhodium Thiavinyl Carbenes from 1,2,3-Thiadiazoles Enable Modular Synthesis of Multisubstituted Thiophenes
Daria Kurandina, Vladimir Gevorgyan*
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Synthesis of Multisubstituted Arenes via PyrDipSi-Directed Unsymmetrical Iterative C–H Functionalizations
Dhruba Sarkar, Anton V. Gulevich, Ferdinand S. Melkonyan, Vladimir Gevorgyan*
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Cu-Catalyzed Transannulation Reaction of Pyridotriazoles: General Access to Fused Polycyclic Indolizines
Yi Shi, Vladimir Gevorgyan*
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Au-Catalyzed Pentannulation Reaction of Propargylic Esters Occurring at C(sp3)–H Site
Roohollah Kazem Shiroodi, Masumi Sugawara, Maxim Ratushnyy, Douglas C. Yarbrough, Donald J. Wink, Vladimir Gevorgyan*
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Synthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines
Roohollah Kazem Shiroodi, Claudia I. Rivera Vera, Alexander S. Dudnik, Vladimir Gevorgyan*
Tetrahedron Lett. 2015, 56, 3251–3254
(Symposium-in-Print: Harry Wasserman)
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General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed C-H Carboxylation
Yang Wang, Vladimir Gevorgyan*
-
Cu-Catalyzed Transannulation Reaction of Pyridotriazoles with Terminal Alkynes under Aerobic Conditions: Efficient Synthesis of Indolizines
Victoria Helan, Anton Gulevich, Vladimir Gevorgyan*
-
Endo-Selective Pd-Catalyzed Silyl Methyl Heck Reaction
Marvin Parasram, Viktor O. Iaroshenko, Vladimir Gevorgyan*J. Am. Chem. Soc. 2014, 136, 17926–17929
(Highlighted in ACS Selects May 2016)
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Rhodium-Catalyzed NH Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2-Picolylamines and Imidazo[1,5-a]pyridine
Yi Shi, Dr. Anton V. Gulevich, Vladimir Gevorgyan*
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1,2-Boryl Migration Empowers Regiodivergent Synthesis of Borylated Furans
Roohollah Kazem Shiroodi, Olesja Koleda, Vladimir Gevorgyan*
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A New Reactivity Mode for the Diazo Group: Diastereoselective 1,3-Aminoalkylation Reaction of β-Amino-α-Diazoesters To Give Triazolines
Alexey Kuznetsov, Dr. Anton V. Gulevich, Prof. Dr. Donald J. Wink, Vladimir Gevorgyan*
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C–H activation: The road less travelled to amination
Olga V. Zatolochnaya, Vladimir Gevorgyan*
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Carboxylate Switch between Hydro- and Carbopalladation Pathways in Regiodivergent Dimerization of Alkynes
Olga V. Zatolochnaya, Dr. Evgeniy G. Gordeev, Dr. Claire Jahier, Prof. Dr. Valentine P. Ananikov, Vladimir Gevorgyan*
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Gold-Catalyzed 1,3-Transposition of Ynones
Roohollah Kazem Shiroodi, Mohammad Soltani, Vladimir Gevorgyan*
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Conversion of 1-Alkenes into 1,4-Diols through an Auxiliary-mediated Formal Homoallylic C–H Oxidation
Nugzar Ghavtadze, Ferdinand S. Melkonyan, Anton V. Gulevich, Chunhui Huang, Vladimir Gevorgyan*
(Highlighted by C&EN and Nature Chemistry)
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Brönsted Acid-Catalyzed One-Pot Synthesis of Indoles from o-Aminobenzyl Alcohols and Furans
Alexey Kuznetsov†, Anton Makarov‡, Aleksandr E. Rubtsov‡, Alexander V. Butin*‡, Vladimir Gevorgyan*
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General and Practical Carboxyl-Group-Directed Remote C-H Oxygenation Reactions of Arenes
Yang Wang, Dr. Anton V. Gulevich, Vladimir Gevorgyan*
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Intramolecular Transannulation of Alkynyl Triazoles via Alkyne–Carbene Metathesis Step: Access to Fused Pyrroles
Yi Shi, Vladimir Gevorgyan*
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Twofold Unsymmetrical C-H Functionalization of PyrDipSi-Substituted Arenes: A General Method for the Synthesis of Substituted meta-Halophenols
Dhruba Sarkar, Dr. Ferdinand S. Melkonyan, Dr. Anton V. Gulevich, Vladimir Gevorgyan*
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Synthesis of Fluoro- and Perfluoroalkyl Arenes via Palladium-Catalyzed [4 + 2] Benzannulation Reaction
Olga V. Zatolochnaya, Vladimir Gevorgyan*
-
Fused Heteroaromatic Dihydrosiloles: Synthesis and Double-Fold Modification
Alexey Kuznetsov, Yoshiharu Onishi, Yoshihiro Inamoto, Vladimir Gevorgyan*
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Metal-Catalyzed Double Migratory Cascade Reactions of Propargylic Esters and Phosphates
Roohollah Kazem Shiroodi, Vladimir Gevorgyan*
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FPyridine Group Assisted Addition of Diazo-Compounds to Imines in the 3-CC Reaction of 2-Aminopyridines, Aldehydes, and Diazo-Compounds
Anton V. Gulevich, Victoria Helan, Donald J. Wink, Vladimir Gevorgyan*
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Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles
Anton V. Gulevich, Alexander S. Dudnik, Natalia Chernyak, Vladimir Gevorgyan*
-
Versatile Reactivity of Rhodium–Iminocarbenes Derived from N-Sulfonyl Triazoles
Dr. Anton V. Gulevich, Vladimir Gevorgyan*
Angew. Chem. Int. Ed. 2013, 52, 1371–1373
(Highlight)
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Palladium-Catalyzed Carbonylative Cyclization/Arylation Cascade for 2-Aroylindolizine Synthesis
Zhou Li, Dmitri Chernyak, Vladimir Gevorgyan*
-
Pd-Catalyzed Modifiable Silanol-Directed Aromatic C-H Oxygenation
Chunhui Huang, Dr. Nugzar Ghavtadze, Benhur Godoi, Vladimir Gevorgyan*
-
General and Selective Head-to-Head Dimerization of Terminal Alkynes Proceeding via Hydropalladation Pathway
Claire Jahier†, Olga V. Zatolochnaya†, Nickolay V. Zvyagintsev‡, Valentine P. Ananikov*‡, Vladimir Gevorgyan*†
-
Synthesis of Fused Heterocycles via Pd-catalyzed Multiple Aromatic C-H Activation Reactions
Anton V. Gulevich, Vladimir Gevorgyan*
-
Organocopper-mediated two-component SN2′-substitution cascade towards N-fused heterocycles
Dmitri Chernyak, Vladimir Gevorgyan*
-
Beyond the Limits: Palladium-N-Heterocyclic Carbene-Based Catalytic System Enables Highly Efficient [4+2] Benzannulation Reactions
Olga V. Zatolochnaya, Alexey V. Galenko, Vladimir Gevorgyan*
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Stereocontrolled 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay Toward Highly Functionalized 1,3-Dienes
Roohollah Kazem Shiroodi, Alexander S. Dudnik, Vladimir Gevorgyan*
-
Double-Fold C-H Oxygenation of Arenes Using PyrDipSi: a General and Efficient Traceless/Modifiable Silicon Tethered Directing Group
Anton V. Gulevich, Ferdinand S. Melkonyan, Dhruba Sarkar, Vladimir Gevorgyan*
-
General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes
Alexey Kuznetsov, Vladimir Gevorgyan*
-
One-Pot Arylative Epoxidation of Ketones by Employing Amphoteric Bromoperfluoroarenes
Zhou Li, Vladimir Gevorgyan*
-
Transition Metal Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems
Dr. Buddhadeb Chattopadhyay, Vladimir Gevorgyan*
Angew. Chem. Int. Ed. 2012, 51, 862–872
(Mini Review)
-
Synthesis of Catechols from Phenols via Pd-Catalyzed Silanol-Directed C–H Oxygenation
Chunhui Huang, Nugzar Ghavtadze, Buddhadeb Chattopadhyay, Vladimir Gevorgyan*
-
Palladium-catalyzed Highly Regioselective C-3 Arylation of Imidazo[1,5-a]pyridine
Chunhui Huang, Alexandros Giokaris, Vladimir Gevorgyan*
Chem. Lett. 2011, 40, 1053–1054
(Special Issue)
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Silanol: A Traceless Directing Group for Pd-Catalyzed o-Alkenylation of Phenols
Chunhui Huang, Buddhadeb Chattopadhyay, Vladimir Gevorgyan*
-
Rh-Catalyzed Transannulation of N-Tosyl-1,2,3-Triazoles with Terminal Alkynes
Buddhadeb Chattopadhyay, Vladimir Gevorgyan*
-
The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes
Chunhui Huang, Natalia Chernyak, Alexander S. Dudnik, Vladimir Gevorgyan*
-
Double Duty for Cyanogen Bromide in a Cascade Synthesis of Cyanoepoxides
Zhou Li, Vladimir Gevorgyan*
-
Palladium-Catalyzed Carbocyclization of Alkynyl Ketones Proceeding through a Carbopalladation Pathway
Natalia Chernyak, Dr. Serge I. Gorelsky, Vladimir Gevorgyan*
-
Cascade carbopalladation-annulation approach toward polycylic derivatives of indole and indolizine
Natalia Chernyak, David Tilly, Zhou Li, Vladimir Gevorgyan*
(Special Issue)
-
Transition Metal-Catalyzed Synthesis of Monocyclic Five-Membered Aromatic Heterocycles
Alexander S. Dudnik, Vladimir Gevorgyan
Catalyzed Carbon-Heteroatom Bond Formation, (ed A. K. Yudin), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. 2010, 317–410
(Book Chapter)
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Transition Metal-Catalyzed Synthesis of Fused Five-Membered Aromatic Heterocycles
Alexander S. Dudnik, Vladimir Gevorgyan
Catalyzed Carbon-Heteroatom Bond Formation, (ed A. K. Yudin), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. 2010, 227–316
(Book Chapter)
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On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped Propargylpyridines
Yuanzhi Xia†‡, Alexander S. Dudnik§, Yahong Li*†, Vladimir Gevorgyan*§
